Teaching Mineralogy with Crystal Structure Databases and Visualization Software
Integrating Research and Education > Crystallography > Identifying Minerals Using Chemical and Crystallographic Data > Directions for CrystalMaker Users > Unknown #7

Unknown #7

Download and view the crystal structure data

  1. Right click on Unknown_7.cif ( 19kB Dec14 04) to download the crystal structure to your computer. (This file was modified from a CIF file in the Crystal Structure Library provided in CrystalMaker).
  2. Start the CrystalMaker program.
  3. Choose the File > Open command, and select the file you just downloaded to view in CrystalMaker.
  4. Click on OK to generate the crystal structure for viewing. This structure is already given to you as a polyhedral model. You should see something like this...

Determine the identity of the unknown

Using your knowledge of crystallography and systematic mineralogy, and manipulating the downloaded structure in CrystalMaker, answer the following questions to deduce the identity of the unknown. Check your answers by clicking on the "show answer" tabs which appear with each question.
Is this mineral a silicate or non-silicate? If silicate, what type?
This is a phyllosilicate (sheet silicate).
showShow question #2
Based on the arrangement of tetrahedral and octahedral layers in this mineral, is this a clay, mica, or something else?
showShow answer
Something else.
showShow question #3
What element occupies the the T-O-T units in this mineral?
showShow answer
Mg, so the mineral is trioctahedral.

...so what mineral is this?
Chlorite - (Mg, Fe)3(Si,Al)4O10(OH)2 dot (Mg,Fe)3(OH)6

Chlorite
Image courtesy of Amethyst Galleries.
The structure is from Phillips et al. (1980) American Mineralogist 65:112-122

Chlorite is the only phyllosilicate with the T-O-T O T-O-T O layered arrangement.

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