Direct identification of hazardous elements in ultra-fine and nanominerals from coal fly ash produced during diesel co-firing
K& Martinello, aacute, Oliveira tia 2014 Science of the Total Environment v470 p444-452

This study has provided an initial assessment of the environmental impacts and potential health effects associated with coal fly ash produced during diesel co-firing. Many hazardous elements that are typically detected by multifaceted chemical characterization by XRD, petrology, FE-SEM/EDS, and HR-TEM/SEAD/FFT/EDS in ultra-fine compounds and nanominerals from the co-fired coal fly ashes (CFAs). It provided an in-depth understanding of coal ash produced during diesel co-firing. Several of the neoformed ultra-fine compounds and nano-minerals found in the coal ashes are the same as those commonly associated with oxidation/transformation of aluminosilicates, carbonates, sulphides and phosphates.

Keywords: fly ash, hazardous elements, nanomaterials, human health exposure