{"text_format":"2","workbook":"xls","n_sheets":11,"sheets":["Read Me","FASH ","CFAS","FAS","MAS2","CAS","MAS1","CMAS","KFMASH","FMAS","MAS(3)"],"not_rendered":{"charts":0,"images":0,"macros":0,"external_links":1,"defined_names":0,"comments":0,"pivot_tables":0},"unopened":[],"bounds":{"document_bytes":16777216,"sheet_cells":100000,"run_cost":"one","rows_first":2000,"rows_last":500,"rows_between":2000,"halvings":0,"cell_chars":16384,"cell_head_chars":4096},"cells_cut":0,"cells_raw":0,"read":"whole","date_system":"1900","formulas":"cached_only"}

{"sheet":"Read Me","index":0,"n_rows":1,"n_cols":1,"rows_kept":1,"cut":false,"hidden":false,"merged":[[0,0,26,7]],"flags":["formulas_cached_only"]}
["This is a spreadsheet to generate balanced chemical reactions that can be used to perform equilibrium calculations using the Berman or Holland and Powell thermodynamic databases. In fact, these can be used quite independently to perform a variety of thermodynamic and kinetic calculations.\n\nThe file consists of several sheets, labelled by the acronym for the chemical system (e.g. MAS, CMAS etc.). For a given system, an area is marked in beige where the stoichiometry of the mineral formula (or, composition in terms of mineral formula units for solid solutions) is to be entered. For example, for quartz (SiO2) one enters \"1\" in the column marked for SiO2 and zero for all other oxides. Forsterite is entered as \"2\" for MgO, \"1\" for SiO2 and zero for all other oxides, and so forth. In any given system, a new mineral can be introduced only in place of one of the existing default options, so that the numbers of rows and columns in the mineral composition matrix remain the same. Once all mineral compositions have been entered, the stoichiometric coefficients for a balanced chemical reaction appears automatically in the column labelled \"stoichiometric coefficients\", If such reactions are possible. Examples are provided to show how to use these to write such reactions - you should verify in each case that the reaction thus obtained is indeed chemically balanced. These stoichiometric coefficients may then be used to calculate the DG of reactions in the thermodynamic calculation spreadsheets - see instructions there on how to proceed further.                                                             \n\n\n\n\n\n\n\n\n"]

{"sheet":"FASH ","index":1,"n_rows":16,"n_cols":9,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Qtz","Ky","FeSt","H2O",null,"Alm"]
[null,"SiO2",1,1,7.5,0,"=",3]
["The Reaction","Al2O3",0,1,9,0,"=",1]
["Matrix A","FeO",0,0,4,0,"=",3]
[null,"H2O",0,0,2,1,"=",0]
[]
[]
[{"$nulls":4},"A-Inverse",null,null,null,"(i.e. the stoichiometric coefficients)"]
[]
[null,null,1,-1,0.375,0,null,3.125,"Qtz"]
[null,null,0,1,-2.25,0,null,-5.75,"Ky"]
[null,null,0,0,0.25,0,null,0.75,"FeSt"]
[null,null,0,0,-0.5,1,null,-1.5,"Water"]
[]
[{"$nulls":5},"3.125Qtz+0.75FeSt=Alm+5.75Ky+1.5H2O"]

{"sheet":"CFAS","index":2,"n_rows":20,"n_cols":9,"rows_kept":20,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Qtz","Fs","An","Alm",null,"Grs"]
[null,"SiO2",1,2,2,3,"=",3]
["The Reaction","Al2O3",0,0,1,1,"=",1]
["Matrix A","CaO",0,0,1,0,"=",3]
[null,"FeO",0,2,0,3,"=",0]
[]
[]
[]
[]
[{"$nulls":5},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,1,0,-2,-1,null,-3,"Qtz"]
[null,null,0,-1.5,1.5,0.5,null,3,"Fs"]
[null,null,0,0,1,0,null,3,"An"]
[null,null,0,1,-1,0,null,-2,"Alm"]
[]
[]
[]
[{"$nulls":5},"3Fs+3An=2Alm+Grs+3Qtz"]

{"sheet":"FAS","index":3,"n_rows":16,"n_cols":8,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Sil","Fs","Qtz",null,"Alm"]
[null,"SiO2",1,2,1,"=",3]
["The Reaction","Al2O3",1,0,0,"=",1]
[null,"FeO",0,2,0,"=",3]
[]
[]
[{"$nulls":4},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,0,1,0,null,1,"Sil"]
[null,null,0,0,0.5,null,1.5,"Fs"]
[null,null,1,-1,-1,null,-1,"Qtz"]
[]
[]
[]
[null,null,null,"1.5Fs+Sil=Qtz+Alm"]

{"sheet":"MAS2","index":4,"n_rows":16,"n_cols":8,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Sil","En","Qtz",null,"Prp"]
[null,"SiO2",1,2,1,"=",3]
["The Reaction","Al2O3",1,0,0,"=",1]
[null,"MgO",0,2,0,"=",3]
[]
[]
[{"$nulls":4},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,0,1,0,null,1,"Sil"]
[null,null,0,0,0.5,null,1.5,"En"]
[null,null,1,-1,-1,null,-1,"Qtz"]
[]
[]
[]
[null,null,null,"1.5En+Sil=Qtz+Prp"]

{"sheet":"CAS","index":5,"n_rows":16,"n_cols":8,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"x2.Wo","x3.An","x4.Qtz",null,"Grs"]
[null,"SiO2",1,2,1,"=",3]
["The Reaction","Al2O3",0,1,0,"=",1]
[null,"CaO",1,1,0,"=",3]
[]
[]
[{"$nulls":4},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,0,-1,1,null,2,"Wo"]
[null,null,0,1,0,null,1,"An"]
[null,null,1,-1,-1,null,-1,"Qtz"]
[]
[]
[]
[null,null,null,"2Wo+An=Qtz+Grs"]

{"sheet":"MAS1","index":6,"n_rows":16,"n_cols":8,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"x2.Fo","x3.En","x4.Spl",null,"Prp"]
[null,"SiO2",1,2,0,"=",3]
["The Reaction","Al2O3",0,0,1,"=",1]
[null,"MgO",2,2,1,"=",3]
[]
[]
[{"$nulls":4},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,-1,-1,1,null,-1,"Fo"]
[null,null,1,0.5,-0.5,null,2,"En"]
[null,null,0,1,0,null,1,"Spl"]
[]
[]
[]
[null,null,null,"2En+Spl=Fo+Prp"]

{"sheet":"CMAS","index":7,"n_rows":20,"n_cols":9,"rows_kept":20,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Qtz","Di","An","Prp",null,"Grs"]
[null,"SiO2",1,2,2,3,"=",3]
["The Reaction","Al2O3",0,0,1,1,"=",1]
["Matrix A","CaO",0,1,1,0,"=",3]
[null,"MgO",0,1,0,3,"=",0]
[]
[]
[]
[]
[{"$nulls":5},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,1,-0.75,-1.25,-0.75,null,-1.5,"Qtz"]
[null,null,0,-0.75,0.75,0.25,null,1.5,"Di"]
[null,null,0,0.75,0.25,-0.25,null,1.5,"An"]
[null,null,0,0.25,-0.25,0.25,null,-0.5,"Prp"]
[]
[]
[]
[{"$nulls":5},"1.5Di+1.5An=Grs+0.5Prp+1.5Qtz"]

{"sheet":"KFMASH","index":8,"n_rows":20,"n_cols":11,"rows_kept":20,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"x1.Qtz","x2.Mus","x3.Ky","x4.Chl","x5.Grt","x6.H2O",null,"Bt"]
[null,"SiO2",1,3,1,5,3,0,"=",6]
["The Reaction","Al2O3",0,3,2,6,2,0,"=",2]
["Matrix A","FeO",0,0,0,2,2,0,"=",3]
[null,"MgO",0,0,0,7,1,0,"=",3]
[null,"K2O",0,1,0,0,0,0,"=",2]
[null,"H2O",0,1,0,8,0,1,"=",2]
[]
[]
[{"$nulls":5},"A-Inverse",null,null,null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,1,-0.5,-1,1.1102230246251565e-16,-1.5,0,null,-0.9999999999999996,"Qtz"]
[null,null,0,0,0,-1.850371707708594e-17,1,0,null,2,"Mus"]
[null,null,0,0.5,-0.33333333333333337,-0.3333333333333333,-1.5,0,null,-4,"Ky"]
[null,null,0,0,-0.08333333333333333,0.16666666666666666,0,0,null,0.25,"Chl"]
[null,null,0,0,0.5833333333333334,-0.16666666666666666,0,0,null,1.25,"Grt"]
[null,null,0,0,0.6666666666666666,-1.3333333333333333,-1,1,null,-2,"Water"]
[]
[{"$nulls":6},"0.25Chl + 1.25Grt + 2Mus = biotite + Qtz + 4Ky + 2H2O"]

{"sheet":"FMAS","index":9,"n_rows":20,"n_cols":9,"rows_kept":20,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Qtz","Opx","Spl","Olv",null,"Grt"]
[null,"SiO2",1,2,0,1,"=",3]
["The Reaction","Al2O3",0,0,1,0,"=",1]
["Matrix A","FeO",0,0.5,0.5,1,"=",1]
[null,"MgO",0,1.5,0.5,1,"=",2]
[]
[]
[]
[]
[{"$nulls":5},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,1,0.5,0.5,-1.5,null,1,"Qtz"]
[null,null,0,0,-0.9999999999999999,1,null,1,"Opx"]
[null,null,0,1,0,0,null,1,"Spl"]
[null,null,0,-0.5,1.4999999999999998,-0.4999999999999999,null,0,"Olv"]
[]
[]
[]
[{"$nulls":5},"Qtz + Opx + Spl = Grt"]

{"sheet":"MAS(3)","index":10,"n_rows":16,"n_cols":8,"rows_kept":16,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
[]
[null,null,"Spl","En","Qtz",null,"Prp"]
[null,"SiO2",0,2,1,"=",3]
["The Reaction","Al2O3",1,0,0,"=",1]
[null,"MgO",1,2,0,"=",3]
[]
[]
[{"$nulls":4},"A-Inverse",null,"x","(i.e. the stoichiometric coefficients)"]
[]
[null,null,0,1,0,null,1,"Spl"]
[null,null,0,-0.5,0.5,null,1,"En"]
[null,null,1,1,-1,null,1,"Qtz"]
[]
[]
[]
[null,null,null,"Spl + En + Qtz = Prp"]