# Stable Isotopes and M&Ms

#### Summary

Students are often confused by the concepts of stable isotope signatures and conventional notation. This activity is designed to introduce students to the del notation (isotopic signature), fractionation, and end member mixing of stable isotopes using familiar objects disguised as isotopes. The activity does not explain the physical manifestation of why isotopic fractionation occurs, but does explain the concepts that one easily observes when interpreting stable isotope data sets.

## Context

#### Audience

Undergraduate majors, upper division

#### Skills and concepts that students must have mastered

Students should be proficient in chemistry.

#### How the activity is situated in the course

Stable isotopes are an important aspect of interpreting ocean processes (biological, physical, chemical) and these processes affect the abundance of heavier isotopes. Since these changes are small but measureable, we use a specific (del) notation to compare samples directly. Changes in (del) are extremely useful in paleoceangraphy studies, carbon cycling, and trophic studies.

## Goals

#### Content/concepts goals for this activity

- Students will be able to determine del values based on given references.
- Students will be able to determine isotopic signatures from end member mixing.

#### Higher order thinking skills goals for this activity

Once students have shown understanding of the fundamental mechanisms that affect stable isotope signatures, they should be able to apply their understanding to new situations.

#### Other skills goals for this activity

## Description and Teaching Materials

In this activity, students will use two types of M&Ms to simulate the behavior of different isotopes. The plain M&Ms will represent the lighter isotope and the peanut M&Ms the heavier isotope. By counting the ratios of lighter and heavier isotopes, students should gain an understanding of del notation, end member mixing and fractionation. A problem at the end of the activity will be used to assess students' understanding and application of the concepts presented here.

- Stable Isotope Activity sheet (Microsoft Word 2007 (.docx) 21kB May31 13)
- Stable Isotope Activity Key (Microsoft Word 2007 (.docx) 16kB May31 13)

## Teaching Notes and Tips

Should may become confused at first, when counting the 'isotopes'.

The key is provided under supporting materials and will help guide students in performing the correct calculations.

The key is provided under supporting materials and will help guide students in performing the correct calculations.

## Assessment

Students successfully completing the activity should be able to determine end member mixing of

They should be prepared to interpret changes in (d) values based on specific isotope applications (i.e.

^{13}C or^{18}O reservoirs through another problem set.They should be prepared to interpret changes in (d) values based on specific isotope applications (i.e.

^{15}N,^{13}C,^{18}O) .